Product ID:GASOLINES-ALL GRADES UNLEADED, 1600
MSDS Date:10/21/1994
FSC:9140
NIIN:00N060727
MSDS Number: BXWZB

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

PETROLEUM DISTILLATES; (PETROLEUM DISTILLATES MFR CAS

Fraction By Weight: 85-98%

OSHA PEL N/K

ACGIH TLV: N/K

>5.0 G/KG

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

>5.0 G/KG

Fraction By Weight: 0-11%

OSHA PEL N/K

ACGIH TLV: N/K

4 ML/KG

Fraction By Weight: 0-15%

OSHA PEL N/K

ACGIH TLV: N/K

TERT-BUTYL ALCOHOL; (TERTIARY BUTYL ALCOHOL) (SARA 313)

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: 0-10%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

BENZENE ETHYL-; (ETHYL BENZENE) (SARA 313)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0-5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHER, TERT-BUTYL METHYL; (METHYL-T-BUTYL ETHER) (SARA 313)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM

ACGIH TLV: S, 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

XYLENE; (XYLENE (MIXED ISOMERS)) (SAR

CAS: 1330-20-7

RTECS: ZE2100000

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:INHAL:MOD RISK OF VAP INTOX.
MAJOR RISK IN ENCLSD SPACES W/POOR VENT:EUPHORIA, LUNG IRRIT &
EDEMA, HDCH, DIZZ, DROW, CONVLS, COMA, CYANOSIS, GENERALIZED
DEPRESSION. SKIN:DEFATTING W/DRYING. EYE: IRRIT. INGEST:BURNING OF
MOUTH & UPPER GI TRACT, VOMIT & DIARR. ABOVE 1 OZ/< 1 OZ
W/RETENTION:GENERAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC MONOGRAPHS, SUPP, VOL 7, PG
20, 1987:GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE
(SUP DATA)
Effects of Overexposure:HLTH HAZS:DEPRESS, SEDATION, RESP DEPRESS,
COMA. CHRONIC:SKIN:DRYING (DERM). INHAL:BENZENE HAS BEEN CLASSIFIED
AS LEUKEMOGEN, & MAY PRDCE ANEMIA, LEUKEMIA FROM RPTD/PRLNGD EXPOS
TO HIGH CONCS. AMERICA N PETROL INSTITUTE SPONSORED CHRONIC INHAL
STUDIES OF UNLEADED GASOLINE VAPS INDICATING UNLEADED GASOLINE IS
(ING 12)
Medical Cond Aggravated by Exposure:PRE-EXISTING DERMATOSES.

First Aid:INHAL:REMOVE TO FRESH AIR. RESP SUPPORT, IF NEC. SEEK MED
AID. SKIN:WASH W/SOAP & WATER. DO NOT WEAR HEAVILY CONTAM CLTHG
BEFORE CLEANING. EYES:FLUSH W/LG VOLS OF WATER FOR AT LST 15 MIN.
SEEK MED AID . INGEST:DO NOT INDUCE VOMIT. SEEK MED AID. NOTE TO
MD:THIS IS LOW VISCOSITY MATL W/SAYBOLT VISCOSITY @ 100F OF <40
SUS. PULM HIGH ASPIR HAZ, POSS PRDCING LIPOID PNEUM IF SWALLOWED &
VOMIT (ING 14)

Flash Point Method:COC
Flash Point:-45F,-43C
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE AND EMITS
VAPORS WHICH MAY BE IGNITED BY OTHER IGNITION SOURCES.

Spill Release Procedures:REMOVE SOURCES OF IGNIT, VENT AREA. SM
SPILLS:TAKE UP W/NON-COMBUST ABSORB SUCH AS FULLERS EARTH/SAND.
PLACE INTO CNTNRS FOR LATER DISP. LG SPILL:CNTN IN EARTHEN DIKES
FOR LATER RECOVERY. CTL IGNIT SO URCES AROUND SPILL AREA.
FIRE-FIGHTING (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD & AWAY FROM
HEAT & FLAME & STRONG OXIDIZERS (NFPA CLASS 1A FLAM). DO NOT STORE
W/STRONG OXIDIZERS.
Other Precautions:CAUTN:EMPTY CNTNRS MAY CNTN PROD RESIDUE WHICH COULD
PRDCE FLAM & EXPLO VAPS. CONSULT APPROP FED, STATE & LOC AUTHS
BEFORE REUSING, RECNDNTING, RECLAIMING, RECYCLING/DISP OF EMPTY
CNTNRS &/OR WASTE RE SIDUES OF PROD. PROT MEASURES (ING 22)

Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE
NIOSH/MSHA APPROVED ORGANIC RESPIRATOR. TLV:TWA: 300 PPM (900
MG/M3) STEL:500 PPM (1500 MG/M3) ACGIH-1987-88.
Ventilation:USE IN WELL VENT AREA. IN CONFINED SPACE, MECH VENT MAY BE
REQ TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 20)
Protective Gloves:OIL IMPERVIOUS GLOVES, SUCH AS (ING 21)
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
WEAR BODY-COVERING GARMENTS TO PVNT PRLNGD/RPTD DIRECT DERM EXPOS.
Work Hygienic Practices:WASH EXPOSED SKIN THORO WITH SOAP AND WATER.
LAUNDER GASOLINE SOAKED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
BP:>79F,>26C (SUBJECT TO SEASONAL CHANGE). VP:7-15 (MEETS SEASONAL RVP
REQS SPECIFIED BY EPA). APPEAR & ODOR:LIQ, GASOLINE ODOR.
MIDGRADE:LIGHT YELLOW, TO PINK, TO LIGHT RED, GASOLINE ODOR. EXPLAN
OF CARCIN:CARCIN. FED REGISTER, VOL 52, PG34460, 1987:OSHA-CANCER
HAZ HUMAN:MYELOID LEUKEMIA, HODGKINS DISEASE, LYMPHOMA.

Boiling Pt:B.P. Text:SUPP DATA
Vapor Pres:SUPP DATA
Vapor Density:3-4
Spec Gravity:0.75 (H*2O=1)
Evaporation Rate & Reference:>1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:UNLEADED:LIGHT YELLOW OR CLEAR LIQ, GASOLINE ODOR.
PREMIUM:RED CLEAR (SUPP DATA
Percent Volatiles by Volume:HIGH

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, STRONG ACIDS, CAUSTICS.
Stability Condition to Avoid:HIGH TEMPERATURE, FLAME.
Hazardous Decomposition Products:CO*2, (CO UNDER INCOMPLETE
COMBUSTION).

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS IT IS
RESPONSIBILITY OF USER TO DETERM IF MATL IS HAZ WASTE AT TIME OF
DISP. CHECK BEFORE DISP TO BE SURE YOU ARE IN COMPLIANCE W/ALL
APPLIC LAWS & REGS. RCRA EMER HOTLINE #:800-424-9346.

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